As a rule, it is not possible to receive a refund from the airline if you do not cancel your flights before the scheduled departure.
If you do not cancel before departure and do not show up for the flight, this is considered a no-show according to the airline's regulations. In such cases, it is unlikely that the airline will grant a refund. In addition, your return flight may be automatically canceled.
If you are certain that you will miss the outbound flight on the day of departure, I strongly recommend that you contact the airline immediately. This way you can find out what alternative arrangements can be made and check the possibility of maintaining your return flight.
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